If we count The Fallen, I suppose we have to count Drift. (Sigh). But yes, let's face it, how many Transformers have had films named after them?
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I thought you were just refering to Classic/Original Gen1 (1984-1992), not neo-Gen1 characters 'retroconned' into Gen1 20 years later. As such, I'd have said Drift as well, as it is a significant character that is portrayed to be 'great', but isn't necessarily seen that way by some fans (like Razorbeast, Stryka, and quite a few others already listed).
the usual suspects like the cast of Beast Wars.
Demolishor (Armada/Energon Demo was the only good thing about the energon toon, the only character to be vaguely interesting. Then they went and lobotomised him. yay :()
Sky-Byte (I'm not 100% on what makes him great, he is just awesome.)
RID Scourge (Awesome enough to forgive the knock-on effect of Nemesis Prime)
BM Strika (Best Fembot Evar!)
Lugnut!
Lockdown!
Let's not forget Prowl2! :D
For me, I'd say probably only Dinobot ranks up there with staples like Starscream, Optimus Prime & the like. BTW BW Primal & Megs are effectively tribute characters.
Dinobot is my number 1 character of all TF's but he was already mentioned so thats why I put forward BM Strika as one of the best female Characters around. Boy did I give that vote for Dinobot button a hammering for the hall of fame induction:D
Primus I guess, all the others I can think of have been mentioned.
Wazzzz-pinator has greatest Legacy! :p
Lio Convoy ;)