Interesting that some of the odd colourings on Onslaught were used later for Dolrailer (Mega-Octane). I prefer the orange on Galvatron's barrel, but I don't know if that's really because it's actually nicer or if it's just because I'm too used to it! Can't... remove... fanboy goggles!!
Superion looks interesting, but too similar to the colours for Ultra Magnus, so I can understand why they changed them. I suspect that for the gestalts, that these might have been their intended Diaclone colours, remembering that these toys were originally cancelled concepts/designs for Diaclone, which Takara dusted off and used for Transformers. And Diaclone Powered Convoy (Ultra Magnus) had entirely different colours - so maybe after they decided on the final colour scheme for Ultra Magnus they then decided to alter the colours for Superion as well.
<shrug> Just completely wild conjecture on my part, but hey - it's fun to guess.![]()