Courtesy of Seibertron.com, via KapowToys, the case assortment for Transformers: Prime Wave 1 is as follows:
Release - 1st November 2011 - US & China

Deluxe

1) Bumblebee x 4
2) Starscream x 2
3) Arcee x 2


Voyager

1) Optimus x 3
2) Bulkhead x 1


Entertainment Battle Packs

1) Optimus & Megatron + Human Characters x 2